<!DOCTYPE chemical_shift_list SYSTEM "chemical_shift_list1.0.dtd">
<chemical_shift_list>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="1" name="HE1"/>
      <atom segid="   A" residue="1" name="HE2"/>
      <atom segid="   A" residue="1" name="HE3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="1" name="H1"/>
      <atom segid="   A" residue="1" name="H2"/>
      <atom segid="   A" residue="1" name="H3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="HG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="HG3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="CE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="SD"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="1" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="2" name="HZ1"/>
      <atom segid="   A" residue="2" name="HZ2"/>
      <atom segid="   A" residue="2" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HE2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HE3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HG3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="NZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="H"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="CE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HD3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="2" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="H"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="ND1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="NE2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="3" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="H"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="ND1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="NE2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="4" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="H"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="ND1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="NE2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="5" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="HD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="HE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="6" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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      <chemical_shift value="2.5" error="0.0"/>
    </spin_system>
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      <chemical_shift value="2.5" error="0.0"/>
    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="12" name="HD12"/>
      <atom segid="   A" residue="12" name="HD13"/>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.559" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.559" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
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      <chemical_shift value="7.17" error="0.0"/>
    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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      <atom segid="   A" residue="15" name="HD12"/>
      <atom segid="   A" residue="15" name="HD13"/>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.681" error="0.007"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.681" error="0.007"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="17" name="HE3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.543" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.543" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.546" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.546" error="0.0"/>
    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="18" name="HG23"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="18" name="HB"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="6.789" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.789" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="2.965" error="0.001"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.965" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="19" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.031" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="20" name="HG2"/>
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      <chemical_shift value="2.307" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="20" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.934" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="22" name="HD22"/>
      <atom segid="   A" residue="22" name="HD23"/>
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      <chemical_shift value="0.765" error="0.004"/>
    </spin_system>
    <spin_system averaging_method="FAST">
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      <atom segid="   A" residue="22" name="HD12"/>
      <atom segid="   A" residue="22" name="HD13"/>
      <chemical_shift value="0.934" error="0.005"/>
      <chemical_shift value="0.765" error="0.004"/>
    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.392" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.392" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="22" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.056" error="0.002"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.056" error="0.002"/>
    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.417" error="0.004"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
      <chemical_shift value="2.942" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
      <chemical_shift value="2.942" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="9.03" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.542" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.542" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="25" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="4.186" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="4.186" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="27" name="HD13"/>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.501" error="0.002"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.501" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="27" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="0.863" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="27" name="HA"/>
      <chemical_shift value="4.132" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.66" error="0.015"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.66" error="0.015"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.95" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.95" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="4.264" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="118.648" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="29" name="HD22"/>
      <atom segid="   A" residue="29" name="HD23"/>
      <chemical_shift value="0.311" error="0.0"/>
      <chemical_shift value="0.144" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="FAST">
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      <atom segid="   A" residue="29" name="HD12"/>
      <atom segid="   A" residue="29" name="HD13"/>
      <chemical_shift value="0.311" error="0.0"/>
      <chemical_shift value="0.144" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="0.814" error="0.006"/>
      <chemical_shift value="-0.29" error="0.001"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="-0.29" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="8.558" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="29" name="HA"/>
      <chemical_shift value="3.442" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="29" name="HG"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="30" name="HA3"/>
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      <chemical_shift value="3.662" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="30" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="30" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="30" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="30" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.779" error="0.005"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.779" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.95" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="HD22"/>
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      <chemical_shift value="6.95" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="HA"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="118.238" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="OD1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="31" name="ND2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="1.641" error="0.002"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.641" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.017" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="HD3"/>
      <chemical_shift value="3.017" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="NE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="4.269" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="HE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="HG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="HG3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="32" name="NH1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="33" name="HE2"/>
      <atom segid="   A" residue="33" name="HE3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="2.64" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.64" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.208" error="0.0"/>
      <chemical_shift value="2.139" error="0.052"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="33" name="HG3"/>
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      <chemical_shift value="2.139" error="0.052"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="33" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="119.792" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="33" name="SD"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="33" name="HA"/>
      <chemical_shift value="4.262" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="34" name="HG21"/>
      <atom segid="   A" residue="34" name="HG22"/>
      <atom segid="   A" residue="34" name="HG23"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="HA"/>
      <chemical_shift value="4.138" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="119.049" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="8.035" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="34" name="HB"/>
      <chemical_shift value="1.909" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="35" name="HA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="35" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="2.324" error="0.0"/>
      <chemical_shift value="1.831" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="HB3"/>
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      <chemical_shift value="1.831" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="HD2"/>
      <chemical_shift value="3.671" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="HD3"/>
      <chemical_shift value="3.671" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="4.461" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="36" name="HG3"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="36" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="36" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="37" name="HG11"/>
      <atom segid="   A" residue="37" name="HG12"/>
      <atom segid="   A" residue="37" name="HG13"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="37" name="HG22"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="HA"/>
      <chemical_shift value="4.405" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="HG21"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="37" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="CG1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="HB"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="37" name="HG23"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="3.68" error="0.01"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.68" error="0.01"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="38" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="38" name="H"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="38" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="38" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="38" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="HB2"/>
      <chemical_shift value="2.615" error="0.005"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="HB3"/>
      <chemical_shift value="2.615" error="0.005"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="HD21"/>
      <chemical_shift value="7.56" error="0.0"/>
      <chemical_shift value="6.75" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="HD22"/>
      <chemical_shift value="7.56" error="0.0"/>
      <chemical_shift value="6.75" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="HA"/>
      <chemical_shift value="4.761" error="0.009"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="N"/>
      <chemical_shift value="118.673" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="OD1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="H"/>
      <chemical_shift value="8.243" error="0.009"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="39" name="ND2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="HD1"/>
      <chemical_shift value="7.2" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="HD2"/>
      <chemical_shift value="7.2" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="7.31" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.331" error="0.001"/>
      <chemical_shift value="2.803" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.331" error="0.001"/>
      <chemical_shift value="2.803" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.9" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="123.149" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="H"/>
      <chemical_shift value="8.823" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="HA"/>
      <chemical_shift value="3.861" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="40" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
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      <atom segid="   A" residue="41" name="HE2"/>
      <atom segid="   A" residue="41" name="HE3"/>
      <chemical_shift value="2.028" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="HB2"/>
      <chemical_shift value="1.913" error="0.0"/>
      <chemical_shift value="1.858" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="HB3"/>
      <chemical_shift value="1.913" error="0.0"/>
      <chemical_shift value="1.858" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="HG2"/>
      <chemical_shift value="2.442" error="0.0"/>
      <chemical_shift value="2.124" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="HG3"/>
      <chemical_shift value="2.442" error="0.0"/>
      <chemical_shift value="2.124" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="CE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="N"/>
      <chemical_shift value="110.965" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="SD"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="H"/>
      <chemical_shift value="7.245" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="41" name="HA"/>
      <chemical_shift value="4.877" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HA"/>
      <chemical_shift value="4.247" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HD3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HG3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="N"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HB3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="42" name="HB2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="HB2"/>
      <chemical_shift value="2.72" error="0.0"/>
      <chemical_shift value="2.642" error="0.003"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="HB3"/>
      <chemical_shift value="2.72" error="0.0"/>
      <chemical_shift value="2.642" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="43" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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      <atom segid="   A" residue="45" name="HD13"/>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.205" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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      <atom segid="   A" residue="46" name="HD23"/>
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      <chemical_shift value="0.934" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="FAST">
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      <atom segid="   A" residue="46" name="HD12"/>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.236" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  </shift_assignment>
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      <chemical_shift value="1.454" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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      <chemical_shift value="0.773" error="0.0"/>
    </spin_system>
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    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error=""/>
    </spin_system>
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      <chemical_shift value="1.773" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.773" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.422" error="0.001"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.422" error="0.001"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.003" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.003" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.875" error="0.012"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.875" error="0.012"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
    <spin_system averaging_method="FAST">
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      <atom segid="   A" residue="52" name="HD13"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.12" error="0.01"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="53" name="HD23"/>
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    </spin_system>
    <spin_system averaging_method="FAST">
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      <chemical_shift value="0.733" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.201" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.041" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.828" error="0.001"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.828" error="0.001"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.549" error="0.006"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.549" error="0.006"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="3.039" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="6.82" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.82" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
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    </spin_system>
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      <atom segid="   A" residue="63" name="HD12"/>
      <atom segid="   A" residue="63" name="HD13"/>
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.384" error="0.0"/>
    </spin_system>
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="3.66" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.66" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="64" name="O"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="65" name="HG21"/>
      <atom segid="   A" residue="65" name="HG22"/>
      <atom segid="   A" residue="65" name="HG23"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="HA"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="OG1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="116.808" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="HB"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="HG1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="65" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="66" name="HG22"/>
      <atom segid="   A" residue="66" name="HG23"/>
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      <chemical_shift value="0.938" error="0.01"/>
    </spin_system>
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="66" name="HG11"/>
      <atom segid="   A" residue="66" name="HG12"/>
      <atom segid="   A" residue="66" name="HG13"/>
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      <chemical_shift value="0.938" error="0.01"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="HA"/>
      <chemical_shift value="4.431" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="N"/>
      <chemical_shift value="123.522" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="CG1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="H"/>
      <chemical_shift value="8.225" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="HB"/>
      <chemical_shift value="2.113" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="66" name="CG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.129" error="0.007"/>
      <chemical_shift value="1.989" error="0.004"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="HB3"/>
      <chemical_shift value="2.129" error="0.007"/>
      <chemical_shift value="1.989" error="0.004"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="HG2"/>
      <chemical_shift value="2.385" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="HG3"/>
      <chemical_shift value="2.385" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="HA"/>
      <chemical_shift value="4.188" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="N"/>
      <chemical_shift value="123.646" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="H"/>
      <chemical_shift value="8.94" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="OE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="67" name="OE1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="HB2"/>
      <chemical_shift value="2.64" error="0.005"/>
      <chemical_shift value="2.477" error="0.003"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="HB3"/>
      <chemical_shift value="2.64" error="0.005"/>
      <chemical_shift value="2.477" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="124.144" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="OD1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="H"/>
      <chemical_shift value="8.901" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="HA"/>
      <chemical_shift value="4.184" error="0.006"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="68" name="OD2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="69" name="HZ2"/>
      <atom segid="   A" residue="69" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="1.447" error="0.002"/>
      <chemical_shift value="1.339" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HB3"/>
      <chemical_shift value="1.447" error="0.002"/>
      <chemical_shift value="1.339" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.75" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HE3"/>
      <chemical_shift value="2.75" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HG2"/>
      <chemical_shift value="0.479" error="0.001"/>
      <chemical_shift value="0.213" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HG3"/>
      <chemical_shift value="0.479" error="0.001"/>
      <chemical_shift value="0.213" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HD2"/>
      <chemical_shift value="1.232" error="0.001"/>
      <chemical_shift value="0.201" error="0.007"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HD3"/>
      <chemical_shift value="1.232" error="0.001"/>
      <chemical_shift value="0.201" error="0.007"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="HA"/>
      <chemical_shift value="3.762" error="0.006"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="NZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="H"/>
      <chemical_shift value="8.486" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="114.695" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="69" name="CE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HD1"/>
      <chemical_shift value="7.219" error="0.004"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HD2"/>
      <chemical_shift value="7.219" error="0.004"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="6.79" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HE2"/>
      <chemical_shift value="6.79" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HB2"/>
      <chemical_shift value="3.128" error="0.0"/>
      <chemical_shift value="2.72" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HB3"/>
      <chemical_shift value="3.128" error="0.0"/>
      <chemical_shift value="2.72" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="OH"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="115.814" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="H"/>
      <chemical_shift value="6.823" error="0.007"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="70" name="HA"/>
      <chemical_shift value="4.349" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HB2"/>
      <chemical_shift value="1.814" error="0.0"/>
      <chemical_shift value="1.748" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HB3"/>
      <chemical_shift value="1.814" error="0.0"/>
      <chemical_shift value="1.748" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HG2"/>
      <chemical_shift value="1.618" error="0.0"/>
      <chemical_shift value="1.46" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HG3"/>
      <chemical_shift value="1.618" error="0.0"/>
      <chemical_shift value="1.46" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HD2"/>
      <chemical_shift value="3.202" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HD3"/>
      <chemical_shift value="3.202" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="NE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HA"/>
      <chemical_shift value="3.129" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HH22"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HH21"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="H"/>
      <chemical_shift value="7.634" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="N"/>
      <chemical_shift value="121.385" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="CZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="NH1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="NH2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HH12"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="71" name="HH11"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HB2"/>
      <chemical_shift value="1.905" error="0.0"/>
      <chemical_shift value="1.692" error="0.011"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HB3"/>
      <chemical_shift value="1.905" error="0.0"/>
      <chemical_shift value="1.692" error="0.011"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HG2"/>
      <chemical_shift value="1.672" error="0.008"/>
      <chemical_shift value="1.559" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HG3"/>
      <chemical_shift value="1.672" error="0.008"/>
      <chemical_shift value="1.559" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HD2"/>
      <chemical_shift value="3.125" error="0.003"/>
      <chemical_shift value="3.052" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HD3"/>
      <chemical_shift value="3.125" error="0.003"/>
      <chemical_shift value="3.052" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="NE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HA"/>
      <chemical_shift value="4.019" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HH22"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HH21"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="H"/>
      <chemical_shift value="7.948" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="N"/>
      <chemical_shift value="115.69" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="CZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="NH1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="NH2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HH12"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="72" name="HH11"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HB2"/>
      <chemical_shift value="2.106" error="0.0"/>
      <chemical_shift value="1.829" error="0.001"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HB3"/>
      <chemical_shift value="2.106" error="0.0"/>
      <chemical_shift value="1.829" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HG2"/>
      <chemical_shift value="1.419" error="0.002"/>
      <chemical_shift value="1.233" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HG3"/>
      <chemical_shift value="1.419" error="0.002"/>
      <chemical_shift value="1.233" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HD2"/>
      <chemical_shift value="2.54" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HD3"/>
      <chemical_shift value="2.54" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="NE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HA"/>
      <chemical_shift value="4.553" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HH22"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HH21"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="H"/>
      <chemical_shift value="7.334" error="0.006"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="N"/>
      <chemical_shift value="116.187" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="CZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="NH1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="NH2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HH12"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="73" name="HH11"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HD1"/>
      <chemical_shift value="6.791" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HD2"/>
      <chemical_shift value="6.791" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HE1"/>
      <chemical_shift value="7.06" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HE2"/>
      <chemical_shift value="7.06" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HB2"/>
      <chemical_shift value="2.556" error="0.005"/>
      <chemical_shift value="2.505" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HB3"/>
      <chemical_shift value="2.556" error="0.005"/>
      <chemical_shift value="2.505" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HZ"/>
      <chemical_shift value="7.075" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="N"/>
      <chemical_shift value="120.787" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CE2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CE1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="H"/>
      <chemical_shift value="7.441" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="HA"/>
      <chemical_shift value="4.299" error="0.01"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="74" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="75" name="HZ1"/>
      <atom segid="   A" residue="75" name="HZ2"/>
      <atom segid="   A" residue="75" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HB2"/>
      <chemical_shift value="1.661" error="0.001"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HB3"/>
      <chemical_shift value="1.661" error="0.001"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HE2"/>
      <chemical_shift value="2.662" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HE3"/>
      <chemical_shift value="2.662" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HG2"/>
      <chemical_shift value="1.051" error="0.002"/>
      <chemical_shift value="0.363" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="75" name="HG3"/>
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  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="1.418" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="75" name="HA"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <atom segid="   A" residue="75" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="76" name="HE2"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.732" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.732" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="77" name="HD2"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="77" name="HE2"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <chemical_shift value="3.05" error="0.004"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.05" error="0.004"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="78" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.711" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.711" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="1.273" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.273" error="0.0"/>
    </spin_system>
  </shift_assignment>
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    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.226" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.226" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="3.777" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="79" name="HB2"/>
      <atom segid="   A" residue="79" name="HB3"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
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      <atom segid="   A" residue="80" name="HG22"/>
      <atom segid="   A" residue="80" name="HG23"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="117.547" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="80" name="H"/>
      <chemical_shift value="8.091" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <atom segid="   A" residue="81" name="HG22"/>
      <atom segid="   A" residue="81" name="HG23"/>
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      <chemical_shift value="0.957" error="0.021"/>
    </spin_system>
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="81" name="HD11"/>
      <atom segid="   A" residue="81" name="HD12"/>
      <atom segid="   A" residue="81" name="HD13"/>
      <chemical_shift value="0.696" error="0.024"/>
      <chemical_shift value="0.957" error="0.021"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="HG12"/>
      <chemical_shift value="1.937" error="0.0"/>
      <chemical_shift value="0.733" error="0.008"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="HG13"/>
      <chemical_shift value="1.937" error="0.0"/>
      <chemical_shift value="0.733" error="0.008"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="HA"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="N"/>
      <chemical_shift value="121.906" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="CG1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="CD1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="HB"/>
      <chemical_shift value="1.867" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="81" name="CG2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="82" name="HB1"/>
      <atom segid="   A" residue="82" name="HB2"/>
      <atom segid="   A" residue="82" name="HB3"/>
      <chemical_shift value="1.502" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="121.718" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="H"/>
      <chemical_shift value="8.138" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="82" name="HA"/>
      <chemical_shift value="4.115" error="0.01"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="HB2"/>
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      <chemical_shift value="2.735" error="0.034"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.77" error="0.005"/>
      <chemical_shift value="2.735" error="0.034"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="N"/>
      <chemical_shift value="119.216" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="OD1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="H"/>
      <chemical_shift value="7.677" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="HA"/>
      <chemical_shift value="4.389" error="0.001"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="83" name="OD2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="84" name="HD21"/>
      <atom segid="   A" residue="84" name="HD22"/>
      <atom segid="   A" residue="84" name="HD23"/>
      <chemical_shift value="0.903" error="0.04"/>
      <chemical_shift value="0.876" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="84" name="HD11"/>
      <atom segid="   A" residue="84" name="HD12"/>
      <atom segid="   A" residue="84" name="HD13"/>
      <chemical_shift value="0.903" error="0.04"/>
      <chemical_shift value="0.876" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="HB2"/>
      <chemical_shift value="1.999" error="0.004"/>
      <chemical_shift value="1.393" error="0.005"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="HB3"/>
      <chemical_shift value="1.999" error="0.004"/>
      <chemical_shift value="1.393" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="N"/>
      <chemical_shift value="119.299" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="CD2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="H"/>
      <chemical_shift value="8.388" error="0.005"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="HA"/>
      <chemical_shift value="4.023" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="84" name="HG"/>
      <chemical_shift value="1.972" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="HB2"/>
      <chemical_shift value="3.984" error="0.001"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="HB3"/>
      <chemical_shift value="3.984" error="0.001"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="OG"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="N"/>
      <chemical_shift value="116.046" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="H"/>
      <chemical_shift value="8.783" error="0.002"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="HA"/>
      <chemical_shift value="4.026" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="85" name="HG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="86" name="HZ1"/>
      <atom segid="   A" residue="86" name="HZ2"/>
      <atom segid="   A" residue="86" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HB2"/>
      <chemical_shift value="1.95" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HB3"/>
      <chemical_shift value="1.95" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HG2"/>
      <chemical_shift value="1.563" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HG3"/>
      <chemical_shift value="1.563" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.658" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HD3"/>
      <chemical_shift value="1.658" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="HA"/>
      <chemical_shift value="4.107" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="H"/>
      <chemical_shift value="7.648" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="N"/>
      <chemical_shift value="120.968" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="86" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="EQUIVALENT">
    <spin_system averaging_method="FAST">
      <atom segid="   A" residue="87" name="HZ1"/>
      <atom segid="   A" residue="87" name="HZ2"/>
      <atom segid="   A" residue="87" name="HZ3"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <atom segid="   A" residue="87" name="HB2"/>
      <chemical_shift value="1.786" error="0.0"/>
      <chemical_shift value="1.415" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HB3"/>
      <chemical_shift value="1.786" error="0.0"/>
      <chemical_shift value="1.415" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HG2"/>
      <chemical_shift value="1.602" error="0.0"/>
      <chemical_shift value="1.536" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HG3"/>
      <chemical_shift value="1.602" error="0.0"/>
      <chemical_shift value="1.536" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HD2"/>
      <chemical_shift value="1.915" error="0.0"/>
      <chemical_shift value="1.399" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HD3"/>
      <chemical_shift value="1.915" error="0.0"/>
      <chemical_shift value="1.399" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="4.128" error="0.003"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="HE3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="H"/>
      <chemical_shift value="7.753" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="N"/>
      <chemical_shift value="118.922" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="CE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="87" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="1.626" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HG3"/>
      <chemical_shift value="1.626" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="NE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HA"/>
      <chemical_shift value="4.093" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HE"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HH22"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HH21"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="H"/>
      <chemical_shift value="7.871" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="N"/>
      <chemical_shift value="119.967" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="CZ"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="NH1"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="NH2"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HD3"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HH12"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="88" name="HH11"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="HB2"/>
      <chemical_shift value="3.903" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="HB3"/>
      <chemical_shift value="3.903" error="0.0"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="OG"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="N"/>
      <chemical_shift value="114.446" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="H"/>
      <chemical_shift value="8.029" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="HA"/>
      <chemical_shift value="4.433" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="89" name="HG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
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      <atom segid="   A" residue="90" name="HB2"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="HB3"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="OG"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="O"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="H"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="HA"/>
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="90" name="HG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
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      <chemical_shift value="2.387" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
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      <chemical_shift value="2.387" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="FLOATING">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="HG3"/>
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      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="C"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
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    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="CB"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="CA"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="127.127" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
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      <chemical_shift value="7.813" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="CG"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="O''"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="CD"/>
      <chemical_shift value="" error="0.0"/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="OE2"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
  <shift_assignment method="STEREO_SPECIFIC">
    <spin_system averaging_method="NONE">
      <atom segid="   A" residue="91" name="OE1"/>
      <chemical_shift value="" error=""/>
    </spin_system>
  </shift_assignment>
</chemical_shift_list>
